Đáp án đúng: B
Giải chi tiết:Cách 1:
\(\begin{gathered} Fe + {H_2}S{O_4} \to FeS{O_4} + {H_2} \hfill \\ 0,225\,\,\,\,\,\,\,\,\,\, \to \,\,\,\,\,\,\,0,225\,\,\,\,\,\,\,\,\,\,\,\,\,(mol) \hfill \\ 10FeS{O_4} + 2KMn{O_4} + 8{H_2}S{O_4} \to 5F{e_2}{(S{O_4})_3} + 2MnS{O_4} + {K_2}S{O_4} + 8{H_2}O \hfill \\ 0,225\,\,\,\,\,\,\,\,\, \to 0,045(mol) \hfill \\ \end{gathered} \)
Cách 2:
\(Fe\xrightarrow{{{H_2}S{O_4}\,loang}}\mathop {Fe}\limits^{ + 2} \xrightarrow{{KMn{O_4}}}\mathop {Fe}\limits^{ + 3} \)
=> V dd KMnO4 = 0,045 : 0,5 = 0,09 lít = 90 ml
Đáp án B