Pt: Ba+2H2O -> Ba(OH)2+H2 (1)
Ba(OH)2+CuSO4 ->Cu(OH)2 \(\downarrow\) +BaSO4 \(\downarrow\)(2)
Ba(OH)2+(NH4)2SO4 ->BaSO4 \(\downarrow\)+2NH3+2H2O (3)
Cu(OH)2\(\underrightarrow{t^0}\)CuO+H2O (4)
BaSO4 \(\underrightarrow{t^0}\) ko xảy ra phản ứng
Theo (1) ta có \(n_{H_2}=n_{Ba\left(OH\right)_2}=n_{Ba}=\frac{27,4}{137}=0,2\left(mol\right)\)
\(n_{\left(NH_4\right)_2SO_4}=\frac{1,32\cdot500}{132\cdot100}=0,05\left(mol\right)\)
\(n_{CuSO_4}=\frac{2\cdot500}{100\cdot160}=0,0625\left(mol\right)\)
Ta thấy: \(n_{Ba\left(OH\right)_2}>n_{\left(NH_4\right)_2SO_4}+n_{CuSO4\:}\) nên Ba(OH)2 dư và 2 muối đều phản ứng hết
Theo (2) ta có: \(n_{Ba\left(OH\right)_2}=n_{Cu\left(OH\right)_2}=n_{BaSO_4}=n_{CuSO_4}=0,0625\left(mol\right)\)
Theo (3) ta có: \(n_{Ba\left(OH\right)_2}=n_{BaSO_4}=n_{\left(NH_4\right)_2SO_4}=0,05\left(mol\right)\)
và \(n_{NH_3}=2n_{\left(NH_4\right)_2SO_4}=0,05\cdot2=0,1\left(mol\right)\)
\(\Rightarrow n_{Ba\left(OH_2\right)}\text{dư}=0,2-\left(0,05+0,0625\right)=0,0875\left(mol\right)\)
a)\(V_{A\left(ĐKTC\right)}=V_{H_2}+V_{NH_3}=\left(0,2+0,1\right)\cdot22,4=6,72\left(l\right)\)
b)Theo (4) ta có: \(n_{CuO}=n_{Cu\left(OH\right)_2}=0,0625\left(mol\right)\)
\(m_{\text{chất rắn}}=m_{BaSO_4}+m_{CuO}=\left(0,0625+0,05\right)\cdot233+0,0625\cdot80=31,2125\left(g\right)\)
